Electron Tunneling in Lithium Ammonia Solutions Probed by Frequency-Dependent Electron-Spin Relaxation Studies
Kiminori Maeda1,‡, Matthew T.J. Lodge1,‡, Jeffrey Harmer1, Jack H. Freed2, and Peter P. Edwards1,* 1Department of Chemistry, Centre for Advanced Electron Spin Resonance, University of Oxford, South Parks Road, Oxford OX1 3QR, United Kingdom 2Department of Chemistry and Chemical Biology, Cornell University, Baker Laboratory, Ithaca NY 14853-1301, USA Electron transfer or quantum tunneling dynamics for […]
Electron Solvation and the Unique Liquid Structure of a Mixed-Amine Expanded Metal: The Saturated Li–NH3–MeNH2 System
Abstract: Metal–amine solutions provide a unique arena in which to study electrons in solution, and to tune the electron density from the extremes of electrolytic through to true metallic behavior. The existence and structure of a new class of concentrated metal-amine liquid, Li–NH3–MeNH2 , is presented in which the mixed solvent produces a novel type […]